ADR lookup / UN 3475

UN 3475 – ETHANOL AND GASOLINE MIXTURE with more than 10 % ethanol or ETHANOL AND MOTOR SPIRIT MIXTURE with more than 10 % ethanol or ETHANOL AND PETROL MIXTURE with more than 10 % ethanol

ADR details for UN 3475 from ADR 2025, Table A: class 3, hazard identification number 33 in the upper half of the orange plate.

UN 3475

ADR (road)

  • 3
Classification
Name and descriptionETHANOL AND GASOLINE MIXTURE with more than 10 % ethanol or ETHANOL AND MOTOR SPIRIT MIXTURE with more than 10 % ethanol or ETHANOL AND PETROL MIXTURE with more than 10 % ethanol
Class3
Classification codeF1
Packing groupII
Labels3
Hazard identification number33
Limited and excepted quantities
Limited quantity (LQ)1 L
Excepted quantity (EQ)E2
Packaging
Packing instructions (8)P001; IBC02
Mixed packing provisions (9b)MP19
Tanks
Portable tanks: instructions (10)T4
Portable tanks: special provisions (11)TP1
Tank code (12)LGBF
Vehicle for tank carriage (14)FL
Carriage
Transport category2
Tunnel restriction code(D/E)
Operation (19)S2; S20
High consequence dangerous goods (1.10.3)
Threshold tank (1.10.3.1.2)3000
Threshold bulk (1.10.3.1.2)a)
Threshold packages (1.10.3.1.2)b)
Environment
Environmentally hazardouspossibly, to be classified by the consignor
Special provisions
Special provisions (6)333; 664
SP 333

Ethanol and gasoline, motor spirit or petrol mixtures for use in spark-ignition engines (e.g. in automobiles, stationary engines and other engines) shall be assigned to this entry regardless of variations in volatility.

SP 664

When substances under this entry are carried in fixed tanks (tank-vehicles) or demountable tanks, these tanks may be equipped with additive devices. Additive devices: - are part of the service equipment for dispensing additives of UN 1202, UN 1993 packing group III, UN 3082 or non-dangerous substances during discharge of the tank; - consist of elements such as connecting pipes and hoses, closing devices, pumps and dosing devices which are permanently connected to the discharge device of the tank's service equipment; - include means of containment which are an integral part of the shell, or permanently fixed to the exterior of the tank or tank-vehicle. Alternatively, additive devices may have connectors for connecting packagings. In this latter case, the packaging itself is not considered part of the additive device. The following requirements shall apply depending on the configuration: (a) Construction of the means of containment: (i) As an integral part of the shell (e.g. a tank compartment), they shall meet the relevant provisions of Chapter 6.8. (ii) When permanently fixed to the exterior of the tank or to the tank-vehicle, they are not subject to the construction provisions of ADR provided they comply with the following provisions: They shall be made of a metallic material and comply with the following minimum wall thickness requirements: Material Minimum wall thickness *) Austenitic stainless steels 2.5 mm Other steels 3 mm Aluminium alloys 4 mm Pure aluminium of 99.80% 6 mm *) For means of containment made with double walls, the aggregate thickness of the outer metal wall and the inner metal wall shall correspond to the wall thickness prescribed. Welding shall be carried out in accordance with the first paragraph of 6.8.2.1.23, except that other suitable methods may be applied to confirm the quality of the welding. (iii) Packagings which are connectable to the additive device shall be metal packagings and meet the relevant construction requirements of Chapter 6.1, as applicable for the additive concerned. (b) Tank approval For tanks equipped or intended to be equipped with additive devices, where the additive device is not included in the original type approval of the tank, the provisions of 6.8.2.3.4 shall apply. (c) Use of means of containment and additive devices (i) In case of (a) (i) above, no additional requirements. (ii) In case of (a) (ii) above, the total capacity of the means of containment shall not exceed 400 litres per vehicle. (iii) In case of (a) (iii) above, 7.5.7.5 and 8.3.3 shall not apply. The packagings may only be connected to the additive device during discharge of the tank. During carriage, the closures and connectors shall be closed so as to be leaktight. (d) Testing for additive devices The provisions of 6.8.2.4 shall apply to the additive device. However, in case of (a) (ii) above, at the time of the initial, intermediate or periodic inspection of the tank, the means of containment of the additive device shall only be subject to an external visual inspection and a leakproofness test. The leakproofness test shall be carried out at a test pressure of at least 0.2 bar. NOTE: For the packagings described in (a) (iii) above, the relevant provisions of ADR shall apply. (e) Transport document Only the information required in accordance with 5.4.1.1.1 (a) to (d) needs to be added to the transport document for the additive concerned. In this case, the remark "additive device" shall be added to the transport document. (f) Training of drivers Drivers who have been trained in accordance with 8.2.1 for carriage of this substance in tanks need no additional training for the carriage of the additives; (g) Placarding or marking Placarding or marking of the fixed tank (tank-vehicle) or demountable tank for the carriage of substances under this entry in accordance with Chapter 5.3 is not affected by the presence of an additive device or the additives contained therein.

Source: BAM – Datenbank GEFAHRGUT, dl-de/by-2-0. ADR 2025 (valid from 1 Jan 2025), BAM status 4 Nov 2024 (modified)

RID (rail)

Name and descriptionETHANOL AND GASOLINE MIXTURE with more than 10% ethanol / ETHANOL AND MOTOR SPIRIT MIXTURE with more than 10% ethanol / ETHANOL AND PETROL MIXTURE with more than 10% ethanol
Class3
Classification codeF1
Packing groupII
Labels3
Hazard identification number33
Special provisions (6)333
Limited quantity (LQ)1 L
Excepted quantity (EQ)E2
Packing instructions (8)P001; IBC02
Mixed packing provisions (9b)MP19
Portable tanks: instructions (10)T4
Portable tanks: special provisions (11)TP1
Tank code (12)LGBF
Transport category2
Express parcelsCE7
Threshold tank (1.10.3.1.2)3000
Threshold bulk (1.10.3.1.2)a)
Threshold packages (1.10.3.1.2)b)
SP 333

Ethanol and gasoline, motor spirit or petrol mixtures for use in spark-ignition engines (e.g. in automobiles, stationary engines and other engines) shall be assigned to this entry regardless of variations in volatility.

Source: BAM – Datenbank GEFAHRGUT, dl-de/by-2-0. RID 2025, status 4 Nov 2024 (modified)

ADN (inland waterways)

Name and descriptionETHANOL AND GASOLINE MIXTURE with more than 10% ethanol / ETHANOL AND MOTOR SPIRIT MIXTURE with more than 10% ethanol / ETHANOL AND PETROL MIXTURE with more than 10% ethanol
Class3
Classification codeF1
Packing groupII
Labels3
Special provisions (6)333
Limited quantity (LQ)1 L
Excepted quantity (EQ)E2
Equipment requiredPP; EX; A
VentilationVE01
Number of cones/blue lights1
SP 333

Ethanol and gasoline, motor spirit or petrol mixtures for use in spark-ignition engines (e.g. in automobiles, stationary engines and other engines) shall be assigned to this entry regardless of variations in volatility.

Source: BAM – Datenbank GEFAHRGUT, dl-de/by-2-0. ADN 2025, status 4 Nov 2024 (modified)

IMDG (sea)

Name and descriptionETHANOL AND GASOLINE MIXTURE with more than 10% ethanol / ETHANOL AND MOTOR SPIRIT MIXTURE with more than 10% ethanol / ETHANOL AND PETROL MIXTURE with more than 10% ethanol
Class3
Packing groupII
Special provisions (6)333
Limited quantity (LQ)1 L
Excepted quantity (EQ)E2
Packing instructions (8)P001
IBC instructions and provisionsIBC02
Portable tanks: instructions (10)T4
Portable tanks: special provisions (11)TP1
EmSF-E; S-E
Stowage categoryE
SP 333

Ethanol and gasoline, motor spirit or petrol mixtures for use in spark-ignition engines (e.g. in automobiles, stationary engines and other engines) shall be assigned to this entry regardless of variations in volatility.

Source: BAM – Datenbank GEFAHRGUT, dl-de/by-2-0. IMDG Code Amdt. 42-24, applicable from 1 Jan 2026, status 9 Dec 2025 (modified)

ICAO (air)

Name and descriptionEthanol and gasoline mixture with more than 10% ethanol / Ethanol and motor spirit mixture with more than 10% ethanol / Ethanol and petrol mixture with more than 10% ethanol
Class3
LabelsLiquid flammable
Packing groupII
Special provisions (6)A156
Excepted quantity (EQ)E2
Packing instruction passenger aircraft353
Max. net quantity passenger aircraft5 L
Packing instruction limited quantity (Y)Y341
Max. net quantity limited quantity (Y)1 L
Packing instruction cargo aircraft364
Max. net quantity cargo aircraft60 L
ERG code3L
SP A156

Ethanol and gasoline, motor spirit or petrol mixtures for use in spark-ignition engines (e.g. in automobiles, stationary engines and other engines) must be assigned to this entry regardless of variations in volatility.

Source: BAM – Datenbank GEFAHRGUT, dl-de/by-2-0. ICAO TI 2025–2026, status 5 Nov 2024 (modified)

We maintain this information to the best of our knowledge, but errors and outdated data are possible. It does not replace the official text of ADR, RID, ADN, the IMDG Code or the ICAO TI, nor a check by a dangerous goods safety adviser. No liability is accepted for the information.

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